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March 2003
The International Reference for Chip-Scale Electronics, Flip-Chip Technology, Optoelectronic Interconnection and Wafer-Level Packaging

Process Makes Electroless Nickel/Gold Wafer Bumping Economical for Flip-Chip Packaging
Information on products or services covered in this article Infomation on products or
services covered in this article

By Dr. Elke Zakel, Pac Tech GmbH, Berlin, Germany; Dr. Thorsten Teutsch and Ron Blankenhorn, Pac Tech USA, Santa Clara, Calif.

Flip-chip technology is a driving force in achieving increased speed and performance along with higher I/O count for a variety of applications. This article discusses a low-cost wafer-level bumping process based on electroless nickel/gold (Ni/Au) under-bump metallization (UBM) that is suitable for all current flip-chip interconnection technologies.

Figure 1. Fifty 200mm wafers are shown undergoing parallel batch processing.

Today, all commercially viable flip-chip methods require that a bump formation be placed on the chip I/O to act as the interconnection. Established techniques, however, like the C4 process(1,2) do not answer the cost requirements for the consumer market.

Alternatively, a selective chemical plating method can significantly reduce costs associated with bumping, since this method does not require masking or metal sputtering. Additionally, this technology enables the parallel processing of multiple wafers, resulting in high throughput.

A cost-effective bumping and assembly process that employs solder stencil printing or direct assembly with ACF or NCP adhesives can also be achieved. (Figure 1 shows a batch of wafers being processed in parallel).

Cost Savings

With the emergence of 300mm wafers, electroless and maskless processes provide basic advantages and cost savings, because their use requires slight or no additional investment.

Additionally, this electroless bumping process presents new possibilities for the manufacture of semiconductors. Because wire bonding onto copper pads is impossible, electroless Ni/Au enables the use of low-cost metallization of copper pads suited for wire bonding.

Figure 2. Process flow for electroless Ni/Au deposition on wafers up to 300mm

Wafer-Level Redistribution

Electroless Ni/Au processes work well for low-cost wafer-level redistribution and wafer-level packaging when combined with additive or semi-additive wafer-level processes. (Figure 2 shows a process flow for the wafer-level CSP and a low-cost redistribution process based on electroless Ni/Au bumping and semi-additive electroless copper plating on a special dielectric.(3))

The electroless bumping of 300mm wafers allows specific cost savings, because more established 300mm equipment processes demand photo-imaging, requiring costly steppers and 300mm sputtering and plating equipment.

By contrast, electroless Ni/Au bumping requires only specially adapted wafer-bumping tanks for the chemical process. Moreover, the dollar investment for the process may be 5-10 times less than the cost to establish a standard electroplating process.

During flip-chip assembly, the Ni/Au bumps protect the Al and act as both an adhesion layer and a diffusion barrier, providing a stable and reliable contact to the aluminum bond pads.(4,5) Additionally, the Ni can also serve as a standoff for chip-on-glass using isotropic conductive adhesive ACF or NCP.(6)

The feasibility and reliability of this bumping process has been established in a series of published technical papers.(7,8) (Figure 3 shows electroless Ni/Au as a basis for an ACF flip-chip assembly, polymeric flip-chip assembly (conductive adhesive) and for soldering and DCA applications with different solder alloys.)

State-of-the-Art

Chemical Ni/Au bumping is a wet-chemical and maskless process. With this well-established manufacturing process, all wafer types can be bumped with a standard process and will result in excellent quality. Using a specially designed bumping line, wafers from 100mm to 300mm in diameter can be plated.

The basic electroless nickel bumping process can be performed with standard, available chemicals for simple test structures/test dies without inner circuitry.

Figure 3. Electroless Ni/Au under-bump metallization can be employed for flip-chip assembly processes.

When applied to functional wafers with complex inner electrical structures, different metallization, and different passivations, however, the process requires specific proprietary chemical compositions and know-how to achieve reproducible and reliable result.

Electroless nickel is employed in industry for a wide range of applications in which aluminum work pieces are plated with nickel. The equipment available for these standard processes, based on large work pieces or PC boards, is unsuitable for wafer bumping.

Modular Wafer Bumping Line

To meet the specific requirements for wafer bumping, a modular electroless nickel wafer bumping line, The PacLine2000, has been developed. Each module can process batches of fifty 200mm or twenty-five 300mm wafers. Automated wafer handling and processing were implemented in the system for higher throughput. (Figure 4 shows the 300mm equipment with wafer loader, reloader and robot handling systems.)

Throughput is governed by the desired thickness of electroless Ni/Au. For UBM, 5µm nickel is typically required. The average processing time is 20 minutes, which translates to one-hundred-fifty 200mm or seventy-five 300mm wafers per hour. Optical microscopy, profilometer measurements and shear tests verify bump quality.

The minimum bump height is 1µm for a closed and voidless nickel layer, because the pad-to-pad spacing limits the maximum height.

The bump height must not be larger than one-half the pad spacing minus 5µm to avoid short circuits between neighboring pads by overgrowing nickel. A UBM height of 5µm is recommended for flip-chip soldering. (The Ni/Au bump characteristics are summarized in Table 1. Table 2 compares solder bumping methods.)

Table 1. Ni/Au Bump Characteristics
Bump Characteristic Specification
Recommended height for FC soldering 5µm
Maximum height ≤1/2 pad spacing -5µm
Material NiP 10%
Resistivity 70 µΩcm
Hardness 550 mHV
Adhesion to Al 100x100 µm2 pad >100g (typ.150g)
Au coating thickness
0.05 – 0.5µm

Design rules(9) have been defined for achieving reliable and reproducible results using electroless Ni/Au bumping of several types of wafers from 100mm to 1300mm, as pad materials AlSi 1%, AlSi 1% Cu 0.5%, AlCu 2% and other alloys of these metals were investigated.

Table 2. Attributes of Various Solder Bumping Techniques
  Electroplating Stencil Printing Laser Jetting
Tooling Requirement Mask Stencil None
Capital Cost Very High Medium Low
Equipment 1. Sputtering
2. Mask Aligner
3. Plating Tool
4. Reflow Oven
1. Printer
2. Reflow Oven
3. Flux Cleaning
1a. SB2-SM or
1b. SB2-Jet
Throughput High Very High Medium
Flux No Yes No
Local Reflow No No Yes
Mechanical Contact
Yes Yes No
3D Packaging No No Yes
Solder Alloy Flexibility Low Medium High

All bump types have been processed with acceptable results; nevertheless, there are some restrictions on the wafers to be nickel bumped. The aluminum bond-pad thickness should be 0.8µm or more in order to have sufficient Al after cleaning and activation. There are no limits to passivation thickness, but the passivation must be defect-free.

Cracks cause a growth of nickel that may produce a short circuit. This will also occur on parts of a wafer surface that were scratched by improper handling. Nickel also grows on silicon that is not covered by an oxide or passivation.

Die Attach

As alternatives to adhesive assembly techniques, the use of a tall Ni/Au bump and ACF or NCP standard solder reflow processes represent the most important die attach methods.(10)

Figure 4. PacLine 2000 for 300mm wafers

Ni/Au UBM is very flexible for use with different 300mm-capable soldering processes and applications. When electroless Ni/Au is combined with solder stencil printing, and solder paste is deposited through a metal stencil, an attractive solder bumping process results.

Typical solder pastes include Pb37Sn63 alloys with particle sizes below 20µm. Low-alpha solder pastes with particle counts below 0.002cph/cm2 are also available.

Another interesting possibility for applying solder bumps on a wafer is by attaching preformed solder balls. This attachment can be achieved with a solder gang-placement method.

Today's demands for packaging of optoelectronics and MEMS devices can no longer be met with standard, flux-based processes that use a long-duration temperature reflow profile and require excessive mechanical handling steps.

These devices require fluxless soldering and no thermal stresses or mechanical contact, which could damage sensitive membranes in MEMS or optical components. Some applications, moreover, require 3D packaging and selective solder applications in 3D structures. These specific needs can be met, however, by a laser-based solder jetting technology.

Summary

In summary, the electroless Ni/Au bumping process, especially when employed to process 300mm wafers, offers a powerful roadmap for flip-chip interconnections in consumer products. The main challenge to electroless Ni/Au as a UBM in the near future is the reduction of pitches to below 50µm.

The development of solder application techniques, such as ball placement in this fine-pitch area, will continue. In addition, the trend toward lead-free or low-alpha solders for stencil printing will continue. An additional challenge will be a strategy of implementing test and known-good die in a process flow for electroless Ni/Au bumping.

References

1. D. De Haven, "Controlled Collapse Chip Carrier (C4), an Enabling Technology," Proc. 1994 Elec-tronic Components and Technology Conference, Washington D.C., 1994, pp. 1-6.

2. L. F. Miller, "Controlled Collapse after Reflow Chip Joining," IBM J. Res. Develop., Vol. 13 (1969), pp. 239-250.

3. T. Teutsch, T. Oppert, E. Zakel, et al., "Wafer-Level CSP Using Low-Cost Redistribution Layers," Proc. 2000 Electronic Components and Technology Conference, Las Vegas, Nevada,

4. T. Oppert, E. Zakel, T.Teutsch, "A Roadmap to Low-Cost Flip Chip and CSP Using Electroless Ni/Au," Proc. IEMT/IMC Symp., Omiya, Japan, 1998.

5. G. Motulla, "A Low Cost Bumping Service Based on Electroless Nickel and Solder Printing," Proc. IEMT/IMC Symp., Omiya, Japan, 1997.

6. M. Vrana, J. De Baets, A. Van Calster, et al., "An Anisotropic Adhesive Flip Chip Technology for LCD Drivers," Proc. SID Conference, 1996.

7. See reference 4.

8. See reference 6.

9. Pac Tech, design rules [www.pactech.de]

10. T. Oppert, T. Teutsch, L. Titerle, et al., "Placement and Reflow of Solder Balls for FC, BGA, Wafer-Level CSP, Optoelectronic Components and MEMS by Using a New Solder Jetting Method," Proc. IMAPS Symp., Denver, Sep. 3-6, 2002.

Dr. Zakel is co-founder and president of Pac Tech GmbH. She was department leader and senior researcher at Fraunhofer Institute and the Technical University of Berlin, where she received her doctorate in material science. She has authored many papers and filed patents on wafer bumping and flip-chip interconnections. [zakel@pactech.de]

Dr. Teutsch is chief technology officer for Pac Tech USA. He received his doctorate in physical chemistry from the Fritz-Haber Institute of the Max-Planck Society. Prior to moving to the U.S., he served with Pac Tech GmbH. [teutsch@pactech-usa.com]

Mr. Blankenhorn is president of Pac Tech USA. His industry experience includes more than two decades of sales and marketing in high technology. He earned a master's degree from Stanford University.[ron@pactech-usa.com]

 
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